The former World Cup winners in 2010 played out a 3-3 draw with Portugal during his debut match claimed a narrow 1-0 win over Iran before battling Morocco to a 2-2 draw.
They finished top of Group B but suffered a shock elimination by hosts Russian Federation in the last 16 last Sunday in a penalty shoot-out after a 1-1 draw.
He was appointed just two days before the World Cup started after Julen Lopetegui was sacked amid the controversy of Real Madrid announcing that Lopetegui would become Madrid's new manager after the tournament.
"The Federation want to highlight the professional and human values of an extraordinary athlete to whom we wish the best of fortunes".
Andres Iniesta, the former Barcelona great who scored the winning goal in the 2010 World Cup final, retired from the worldwide team after the defeat to Russian Federation.